Anyone can do maintenance on a GA experimental but only you as the builder can sign the maintenance release, provided you have passed an approved maintenance procedures course (which is all about rules and regulations, not maintenance).
Again, anyone can do the maintenance on a GA experimental. If the aircraft you bought is similar to one you have previously built (eg, built RV-4, bought RV-8), then you can also sign the maintenance release (as above). If you haven't got that background, then you need to get a LAME to sign the maintenance release.
rgmwa