That's getting a bit academic. I'm not building a 11kv transmission tower! Everyone uses copper cables for starter motors. so will I.
Lucas sometimes used aluminium for field windings in their starters. The copper tag of the brushes were spot welded on. If you had to replace them, normally you would cut off the brush, leaving a bit of the copper tag behind. Then bind the new brush on with a single stand of copper wire and solder.
One place I worked at did a lot of vintage stuff, and someone had a roll of 'aluminium' solder. Not sure what it was made from. Apparently unobtainium, because you couldn't buy it anymore. But it could solder copper to aluminium! I never used it though.